Cinetique de l’adsorption du phenol en couche fluidisee de charbon actif R. Ganho. Thèse Docteur-Ingénieur, Université Paul-Sabatier, Toulouse (). [17] . Etude de l’adsorption de complexes cyanures sur charbon actif .. They demonstrated that the removal of these metal ions followed the descending order : Cu\. Request PDF on ResearchGate | Modélisations des isothermes d’adsorption sur charbon actif de composés aromatiques en solution aqueuse | Models have.

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Molecules are adsorbed and immobilized onto sites of different energies They do, however, have some interactions with other adsorbed molecules. The interactions between this solution and the solid were characterized by several methods: Langmuir and Freundlich parameters for the adsorption of the basicred dye on sawdust.

The limiting step is the diffusion through a film at the start of the reaction, which is followed by the diffusion-adsorption into the porous structure in a region close to equilibrium.

The linearized Clark equation 16 gives a good representation of experimental results fig.

This modification depends on the nature and pressure of the gas used. The percentage is constant alter 35 cm depth of the activated carton in agreement with the electon microscopy study that showed that the flora was only present in the 10 first centimeters.

Intra-particle diffusion is the rate-limiting step in the process of adsorption beyond 60 min contact time. The thermodynamic study has shown that the data tiken from adsorption of the dicyanoaurate ions onto the carbon can be fitted by LANGMUIR’s isotherm, which has been generalized for several types of thesex.

La sciure de bois contient des groupements polaires tels que les hydroxyles et les carboxyles. Adsorption dynamique en phase liquide sur charbon actif: Application of the intra-particle diffusion model to the adsorption of the basic red dye on sawdust. For the kinetics study, perfectly stirred avtif experiments were carried out after adjustment of the parameters influencing the system, such as the pH, adsorbent dosage and initial dye concentration.


Adsorption isotherm of the basic red dye on sawdust. Application of the pseudo-second order model to the adsorption of the basic red dye on sawdust. The point chrbon zero charge pH PZC of sawdust.

The No value is similar to those obtained from the other equations. The linear flow rates were 3. Revue des sciences de l’eau 24, n o 2 Effect of temperature on the adsorption of the basic red dye on sawdust. Adsorption study in a solid system: Mohamed Zarrouki 1, 2 Details. With the use of the two parameters, the break-through curves have been recalculated fig.

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Have you forgotten your login? Kinetic modeling of the adsorption of basic dyes by kudzu. The agreement is only for the low values of C in the break-through curves. The chemical surface reaction was fitted to a pseudo-second order equation, with very high regression coefficients.

Effect of contact time on the adsorption of the basic red dye on thwses.

Étude cinétique et thermodynamique de l’adsorptio… – Revue des sciences de l’eau – Érudit

Tuesday, October 23, – 2: The adsorption rate of the dicyanoaurate ion onto the activated carbon was studied as a function of several physical-chemical parameters: These groups consist of the sites responsible for the complex adsorption.

Two parameters A and r are determined by regression equations ; we proposed a simple method to calculate A and thses by a linearization of the preceding equation eq. The model developed by CLARK is based on the use of e mass-transfer concept in combination with the Freundlich isotherm fig. adsorptioh


The A parameter is related to the depth Z of the adsorbant: The use of this model is facilitated by our linearization and the case of acsorption phenomena: The kinetics, thermodynamics and isotherms of the adsorption were used to identify the retention mechanisms. Revue des charbom de l’eau 6, n o 1 Experimental results were modelled according to kinetic equations representing pseudo-first order, pseudo-second order reactions, as well as equations for external and intra-particle diffusion.

The general equation is equation Tuesday, July 16, – 2: Values of the kinetic constants for the adsorption of the basic red dye on sawdust. Their is good agreement. Mohamed Zarrouki 1, theees AuthorId: Wednesday, April 5, – As early as BOHART and ADAMS presented differential equations which govern the dynamics of the adsorption of vapours and gases on fixed beds and the final result, applied to the liquid-solid phase, yields the kinetic adsorption rate k and the maximum adsorption capacity No eq.

Activated carbon-dicyanoaurate ion solution. B value can be determined with the different columns fig. These methods have given information about the nature of the functional groups which are on the surface of the activated carbon.

Activated carbon is used as the adsorbent. This has allowed us to understand the fundamental mechanism of adsorption in a model system which consists of a solution of dicyanoaurate ions and activated carbon. Effect of pH on the adsorption of the basic red dye on sawdust.

Solution d’ion dicyanoaurate-charbon actif.