This method is included in NEMI for informational purposes as it is approved by EPA for regulatory use. Detailed information on this method is not currently. eropoly acid. This is reduced to silicomolybdenum blue that is determined pho- tometrically. The method is analogous to APHA SiO2 D+E, ASTM D, . Find the most up-to-date version of ASTM D at Engineering
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A direct reading spectrophotometer or? It is the skeletal material of diatoms but is not known to play a significant role in the structure of processes of higher life forms. Measurements may be made at nm with a spectrophotometer, or to nm with a?
It may be monomeric or polymeric. This can be compensated for by preparing standards in a matrix similar to that of samples or by using a standard additions technique. NOTE 1—For many natural waters, a measurement of molybdatereactive silica by this test method provides a close approximation of total silica, and, in practice, the colorimetric method is frequently substituted for other more time-consuming techniques.
Check the concentration of this solution gravimetrically. Refer to Appendix X1 for historical information. Such waste waters may also contain organic compounds that may interfere in the color formation. When working with low concentrations of silica, a batch of ammonium molybdate known to produce reasonable blanks, linearity, and reproducibility should be set aside for this purpose.
The type and composition of the silica-containing minerals in contact with the water and the pH of the water are the primary factors controlling both the solubility and the form of silica in the resulting solution. High blanks, nonlinear calibration curves, and poor reproducibility have been observed with some batches of this compound.
Prepare a blank using a In solution it can exist as silicic acid or silicate ion, depending upon pH.
Standard Test Method for Silica in Water
The presence of most silica in natural waters comes from the gradual degradation of silica-containing minerals. It is found as the oxide in crystalline forms, as in quartz; combined with other f859 and metals in a variety of silicates; and in amorphous forms. Current edition approved Feb. Referenced Documents purchase separately The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM D 水中硅测定的标准方法_百度文库
Discard when the color asgm or a precipitate forms. It is applicable to most waters, but some waters may require? For measurements at nm, plot absorbance versus milligrams SiO2 per litre. Calibration and Standardization Unless otherwise indicated, it is intended that all reagents shall conform to the speci? The lower limit of this method aastm 5 mg of silica. The analyte recoveries for the LCS should fall within the control limits of x 6 3S, where x is the IDP amount and S is the standard deviation of the mean recovery established from It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
In contrast, silica may be added as a treatment chemical in some systems, for example, in corrosion control. It is the skeletal material of diatoms but r859 not known to play a signi?
Link to Active This link will always route to the current Active version of the standard. ASTM D95 – For seawater or brines, this test method is applicable only if matched matrix standards or standard addition techniques are employed. The MS should be prepared in accordance with Guide D For seawater or brines, this test method is applicable only if matched matrix standards or standard addition techniques are employed. The presence of most silica in natural waters comes from the gradual degradation of silica-containing minerals.
This test method is useful for concentrations as low as 20? Due to the complexity of silica chemistry, the form of silica measured is defined by the analytical method as molybdate-reactive silica.
ASTM D859 – 16
It is particularly applicable to treated industrial waters. In cooling water systems, silica forms ast when solubility limits are exceeded. Silicon is the most abundant 8d59 in igneous rocks and is the characteristic element of all important rocks except the carbonates.
This standard has been approved for use by agencies of the Department of Defense. It is particularly applicable to treated industrial waters. Silica may exist in suspended particles, as a colloid, or in solution. Type II water was speci? NOTE 4—Batch to batch variations in ammonium molybdate have been found to affect results at low concentrations below 0. Last previous edition approved in as D — Link to Active This link will always route to the current Active version of the standard.
Quality Control QC Referenced Documents purchase separately The documents listed below are referenced within the subject standard but are not provided as part of the standard. The LCS is a d8559 of method analytes of known concentration added to a matrix that sufficiently challenges the Test Method.
Summary of Test Method 4. In solution it can exist as silicic acid or silicate ion, depending upon asm.
Silicon is the most abundant element in igneous rocks and is the characteristic element of all important rocks except the carbonates.
Note 1—For many natural waters, satm measurement of molybdate-reactive silica by this test method provides a close approximation of total silica, and, in practice, the colorimetric method is frequently substituted for other more time-consuming techniques.